things i won't work with chlorine trifluoridethings i won't work with chlorine trifluoride

ClF3 will quickly corrode even noble metals like iridium, platinum, or gold, oxidizing them to chlorides and fluorides. Physicists are still trying to solve this mystery. It is hypergolic with every known fuel, and so rapidly hypergolic that no ignition delay has ever been measured. Meaning its capable of rapidly oxidizing things that would normally be considered practically impossible to set aflame, like asbestos. It is shipped as a greenish-yellow liquid. Site design / logo 2023 Stack Exchange Inc; user contributions licensed under CC BY-SA. (The list of people who were blown up or poisoned while trying to do so is impressive). [clarification needed][citation needed]. Since the war, the compound has been banned under the Chemical Weapons Convention. By clicking Accept all cookies, you agree Stack Exchange can store cookies on your device and disclose information in accordance with our Cookie Policy. Boils at 53F. Flash of fireworks, ship shell floating off into space, crew subjected to the horrors of radiation. How? That process, I should add, would necessarily have been accompanied by copious amounts of horribly toxic and corrosive by-products: its bad enough when your reagent ignites wet sand, but the clouds of hot hydrofluoric acid are your special door prize if youre foolhardy enough to hang around and watch the fireworks. . "Do not be omitting the stirring, then. Exposure to larger amounts of ClF3, as a liquid or as a gas, ignites living tissue, resulting in severe chemical and thermal burns. Pretty self-explanatory. And countermeasures similar to those of ICBMs can be built into ClF3 factory-bomb (decoys, antiradar measures, etc.). Sensory loss has a profound effect on millions of peoples everyday lives. To subscribe to this RSS feed, copy and paste this URL into your RSS reader. @ozone - it's false. The only time I see either of them in the synthetic chemistry literature is when a paper by Shlomo Rozen pops up (for example), but despite his efforts on its behalf, I still won't touch the stuff.And if anyone needs any more proof as to why, I present this video, made at some point by some French lunatics. It is also hypergolic with such things as cloth, wood, and test engineers, not to mention asbestos, sand, and waterwith which it reacts explosively. Thats one of those statements you dont get to hear very often, and it should be enough to make any sensible chemist turn around smartly and head down the hall in the other direction. One that I want to point out is that for this weapon to be effective you must first hit an enemy with the shell. Storing it aboard your spaceship is too risky, sure, as other answers have noted. Ill be lacing mine up if anyone tries to bring the stuff into my lab. Safety and Health Would it be possible to use chlorine trifluoride as the payload of an artillery shell? Your email address will not be published. Chlorine Trifluoride is a colorless gas or a white solid with a sweet, suffocating odor. But, of course, the weapon was incredibly dangerous for those carrying it around too, not just those they launch it at. But using sword-chucks during WW2 won't do anything useful. The same isn't true in a war zone, where speed is of the essence. You just have to stay safe from it before and while you apply it. But now, thanks to neuroprosthetic technology we can tap into nerve and brain function, and rewire these lost connections. It is used in rocket fuels and in processing nuclear . And thats at room temperature. A little bit of danger can be exciting. How massive does earth need to be to start fusion reaction? Minecraft Legends is gaming at its best - fun, welcoming, evolving, easy to play but endlessly difficult to master. The spaceship gets hit by something, causing a breach that releases chlorine trifluoride and unleashes hell. (A courier ship on a desperate run carrying "plans" fights a desperate battle to protect them, not surrendering, finaly self destructing in a desperate sacrifice yada, yada etc. 1) Chlorine Trifluoride is the most flammable gas. It's just that it may have been a bit too reactive. I really have to salute the dedication involved in finding that out, though - after two or three violent explosions, you or I might be tempted to just say that we couldn't determine the products of the reaction. Sure, it can kill people and destroy equipment. originally appeared on Quora: the place to gain and share knowledge, empowering people to learn from others and better understand the world. Arsenic Arsenic is a metalloid element that forms a number of poisonous compounds. Imagine flying through space and inconveniently running through a cloud of this stuff. How can I make inferences about individuals from aggregated data? John Howard, M.D. Chlorine trifluoride appears as a colorless gas or green liquid with a pungent odor. I mean, maybe? Required fields are marked *. Small Species - What weapons would make sense? Each mask is provided with a rectangular pane (7 x 3 inches) of shatter-proof glass. Any equipment that comes into contact with ClF3 must be meticulously cleaned and then passivated, because any contamination left may burn through the unfluorinated material faster than it can re-form. We have Plexiglas, a rubber glove, clean leather, not-so-clean leather, a gas mask, a piece of wood, and a wet glove. That means that it can potentially go on to burn things that you would normally consider already burnt to hell and gone, and a practical consequence of that is that itll start roaring reactions with things like bricks and asbestos tile. But thats how you get it to react with oxygen to make a product thats worse in pretty much every way. They isolated the compound chlorine trifluoride (ClF3), which was liquid (check!) If it's not perfectly treated, then kaboom goes the vessel. This liquid chemical is so corrosive that it can virtually burn through anything. Chlorine trifluoride is one of the most horrifying substances on Earth. This oxidizing power, surpassing that of oxygen, causes ClF3 to react vigorously with many other materials often thought of as incombustible and refractory. Things I won't work with: Dioxygen Difluoride. Obviously the first question to answer here is how chlorine trifluoride is somehow able to cause asbestos, a substance that is known for being almost completely fire retardant, to catch on fire. "Until they blow up", you say. So this is true cost Peter is one Coffee Table to one. The collection is called Things I Wont Work With and is a hair-raising categorization of substances that Dr. Lowe in particular refuses to go anywhere near. It has a heat capacity of 63.9 J K -1 mol -1. because of the formation of a thin film of insoluble metal fluoride which protects the bulk of the metal, just as the invisible coat of oxide on aluminium keeps it from burning up in the atmosphere. Handling concerns, however, severely limit its use. Stack Exchange network consists of 181 Q&A communities including Stack Overflow, the largest, most trusted online community for developers to learn, share their knowledge, and build their careers. It's a spacious game preserve, that territory, and over the gate is the ornate motto Noli me tangere. This article first appeared on Curiosity.com. It has a density of 3.779 g/L. Get our latest posts and insights delivered directly to your inbox. bad. 2.1.2 Odor 2.1.3 2.1,11 Chlorine trifluoride odor has been re~orted as both sweet ~nd pungent, similar to chlorine or mustard. Chlorine trifluoride is one of the most horrifying substances on Earth. Put those in a warhead" and "what would happen if you used this stuff in a mine field, assuming some unobtainium even it couldn't react with?". The union one twin thing. However, a few experimenters have had a go with dioxygen difluoride and survived. Or the nuclear materials are unavailable or prohibitively expensive for some reason, so chemical weapons become a necessity, and the strongest oxidizer all can come into play. Powered by Tumblr. But even A. G. Streng chickened out of reacting it with sulfides. There is nothing that spontaneously produces it. Chlorine Trifluoride-producing microorganisms. Connecting with the enemy ship is the hardest part. It burned its way through a foot of concrete floor and chewed up another meter of sand and gravel beneath, completing a day that Im sure no one involved ever forgot. If you liked this article, you might also enjoy: Melissa writes for the wildly popular interesting fact website TodayIFoundOut.com. But if you start talkin' chlorine trifluoride, we'll take a hard pass, thanks. We have Plexiglas, a rubber glove, clean leather, not-so-clean leather, a gas mask, a piece of wood, and a wet glove. Screen capture done with Camtasia Studio 4.0. These reactions are often violent, and in some cases explosive, especially with flammable materials. How can Bronze Age people make hazmat gear for chlorine trifluoride? Some of this, under ordinary circumstances, might be considered protective equipment. Untitled - Free download as PDF File (.pdf), Text File (.txt) or read online for free. To give one example, the (theoretical) result of reacting dioxygen difluoride with hydrogen sulfide would be a violent exothermal explosion (~433kcal per mol about twice that of TNT) blowing out a burning cloud of hydrogen fluoride, a gas that dissolves human tissue on contact, starting with your lungs and eyeballs. An average 70 kg human being only would have to take around 100 nanograms of this protein to die (it has an LD 50 of 1. . Halogens can be stored and transported relatively safely even now, so for spacefaring people packing two containers and a reactor together should not pose much of a problem. Chernobyl's causes are well-documented by international agencies; it was a long series of human errors. Notably tough elements like titanium and tungsten are also regarded as being wholly unsuitable to storing the chemical because they set on fire as soon as they come into contact with it. It reacts with water to form chlorine and hydrofluoric acid with release of heat. AAAS is a partner of HINARI, AGORA, OARE, CHORUS, CLOCKSS, CrossRef and COUNTER. If you've seen a shooting star on a recent stargazing jaunt, you've spotted the very beginning of the Orionids meteor shower. consequat. Space requires a lot of energy, so if it's at larger scale than us earthlings going around the Solar system, a spaceship has access to some energy source probably more powerful than nuclear or thermonuclear. [5] Soluble in CCl 4 but can be explosive in high concentrations. This sample was then exposed to 100% chlorine trifluoride gas at 500C and at the flow rate of 50 sccm for 10 minutes. If you throw water on the source of the problem, it will get worse. (Yes, people have actually done this.) To work with the substance that is given off you have to cool it down quickly to around -180C or colder, since it tears itself to pieces at anything approaching normal temperatures. So the obvious solution is to drop a machine producing ClF3 upon your enemy. Chlorine trifluoride Safety Data Sheet E-4581 according to the Hazardous Products Regulation (February 11, 2015) Date of issue: 10-15-1979 Revision date: 01-01-2021 Supersedes: 07-05-2016 . Turns out there is: chlorine trifluoride, and he quotes a colleagues description: It is, of course, extremely toxic, but thats the least of the problems. Stargazers rejoice! Of course, the enemy can try to destroy the bomb before the reaction has even started, just like missile defense this days tries to stop ICBMs. We have Plexiglas, a rubber glove, clean leather, not-so-clean leather, a gas mask, a piece of wood, and a wet glove. Well, it's been a bit too serious around here this week. It also has a nice fat density, about 1.81 at room temperature. Staying power, that's what I call it. It occurs as a ligand in the complex CsF(ClF3)3.[15]. Gibbs free energy is -123.0 kJ mol -1. What's that? Image by Koisny under Creative Commons license. Your email address will not be published. . 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Derek Lowes commentary on drug discovery and the pharma industry. Use a back flow preventive device in the piping. Only 30 tons of the chemical were ever made, and it was thankfully never used in combat. The stuff would rip the hull off your ship. ), perchloryl fluoride (! Okay, these are the values the ranges So 1st 70 days Over- # five which belongs to this. These azidonauts endorse:". 7790-91-2). . Here is a chemistry tip. Scientists have recommended the RTS,S vaccine for children in sub-Saharan Africa and other high-risk areas to prevent one of the worlds oldest and deadliest infectious diseases. . Speaking of which, when chlorine trifluoride comes into contact with water, it will react explosively with it and as a fun byproduct creates large amounts of dangerous gasses such as hydrofluoric acid and hydrochloric acid. Steel, copper, and nickel are not consumed because a passivation layer of insoluble metal fluoride will form which prevents further corrosion, but molybdenum, tungsten, and titanium are unsuitable as the fluorides that they form are volatile. While World War II raged on, the Nazis took interest in CIF3, to nobody's surprise. 5.7M views, 64K likes, 2.1K loves, 892 comments, 15K shares, Facebook Watch Videos from Adds/15: Why is an infant mur.der.red? 13(a-1), by visual inspection. Done on a Dell Dimension laptop computer with a Wacom digital tablet (Bamboo). HDE 226868 is absolutely correct, it would be the height of insanity to use this stuff in space combat but that doesn't mean it wouldn't make one whale of a good story. To subscribe to Today I Found Outs Daily Knowledge newsletter, click here or like them on Facebook here. The following passage by rocket scientist John D. Clark is widely quoted in descriptions of the substance's extremely hazardous nature: It is, of course, extremely toxic, but that's the least of the problem. What ClF3 can do to an enemy spaceship that a good old atomic bomb can't do? Chlorine trifluoride, ClF 3 , or "CTF" as the engineers insist on calling it, is a colorless gas, a greenish liquid, or a white solid. No leather suits this time and (interestingly) no earplugs. I dropped the wrench and blew up the missile!" Have fun. Rejoice, in your enemy's gullibility and that you just cut the head off their science division barely getting your own hands dusty. Rather fortunately, chlorine trifluoride doesnt react with air unless it happens to contain a larger than average amount of water vapor. It reacts with water to form chlorine and hydrofluoric acid with release of heat. @JBH highly reactive and highly explosive substances are useful as weapons because they essentially contain large, concentrated amount of available chemical energy that can be delivered upon the target. National Institute for Occupational. The best answers are voted up and rise to the top, Not the answer you're looking for? A ton of CIF3 was accidentally spilled on a warehouse floor, which caused it to burn straight through a foot (30 centimeters) of concrete and three feet (90 centimeters) of gravel. Its been used in the semiconductor industry to clean oxides off of surfaces, at which activity it no doubt excels. It's difficult to contain and nearly impossible to fight if it starts a fire, and produces extremely toxic byproducts when it reacts with other things. . If your shell is too weak to get through the hull, it would splash against the armor, react with a small amount of the hull material, be explosively ejected by its own reactive byproducts, and disperse into the vacuum of space with minor damage done. It seems that no-one has done so (or at least, no-one has done so and survived in a state to write a paper about it). DHHS (NIOSH) Publication Number 2020-124. CIF3 is its own oxidizer and so doesn't rely on the atmosphere to burn in that sense, but venting the atmosphere will almost certainly remove all of the CIF3, which is gaseous under normal conditions and would be vented along with the atmosphere. "Things I Won't Work With" : Chlorine Trifluoride. Stross is good at postulating alternate causes that sound potentially plausible if you accept a ridiculous starting point. Putting off oil changes and ignoring your check engine light can end up costing you $8,000 or more in major engine repairs later and shorten your vehicle's lifespan by as much as 50,000 miles.. A few of the other things known to not react with chlorine trifluoride include nitrogen, the inert gases and polychlorotrifluoroethylene. For dealing with this situation, I have always recommended a good pair of running shoes. Again, more conventional munitions would probably be sufficient to cripple a ship from the inside, and your ship will probably have some onboard already. This technical report presents the IDLH value for chlorine trifluoride (CAS No. That details the fun you can have with chloride trifluoride, and believe me, it continues (along with its neighbor, bromine trifluoride) to be on the Things I Wont Work With list. Try one more set of practice questions with a slightly more complicated reaction. Say hi any time. Things I Won't Work With: Peroxide Peroxides, Things I Won't Work With: Frisky Perchlorates. Simple Things theme by Dan Hauk. Hydrofluric acid in particular is incredibly dangerous and along with being able to melt things like glass and concrete, can permanently damage your lungs and eyes. This week 've seen a shooting star on a recent stargazing jaunt, you might also:..., CHORUS, CLOCKSS, CrossRef and COUNTER of practice questions with a Wacom digital tablet ( )! Found Outs Daily knowledge newsletter, click here or like them on here... For chlorine trifluoride doesnt react with air unless it happens to contain a larger average... Be lacing mine up if anyone tries to bring the stuff into my.... People have actually done this. ) fat density, about 1.81 at room temperature possible to use chlorine is! Goes the vessel ignition delay has ever been measured Outs Daily knowledge newsletter, click or. ( Bamboo ) be possible to use chlorine trifluoride gas at 500C and at the rate. Used in rocket fuels and in processing nuclear very beginning of the problem, it 's just it! Are often violent, and so rapidly hypergolic that no ignition delay ever... Nice fat density, about 1.81 at room temperature OARE, CHORUS, CLOCKSS, CrossRef and COUNTER directly your... Situation, I have always recommended a good pair of running shoes each is... You get it to react with air unless it happens to contain larger! Text File (.txt ) or read online for Free # five which belongs to RSS. Nice fat density, about 1.81 at room temperature tablet ( Bamboo ) doubt excels of shatter-proof glass division getting! Of human errors hazmat gear for chlorine trifluoride is the most horrifying substances on Earth x 3 inches of... Clf3 upon your enemy they isolated the compound chlorine trifluoride, we 'll take a hard pass, to... And over the gate is the ornate motto Noli me tangere in cases! While you apply it trifluoride odor has been banned under the chemical were ever,... The gate is the most flammable gas also has a profound effect on millions of peoples everyday lives considered... Good at postulating alternate causes that sound potentially plausible if you 've spotted the very beginning the. Point out is that for this weapon to be effective you must hit! 10 minutes, however, severely limit its use at which activity it no doubt.. Isolated the compound has been re~orted as both sweet ~nd pungent, similar to chlorine or.... Go with Dioxygen Difluoride and survived the complex CsF ( ClF3 ), which was liquid (!. Jaunt, you say to react with oxygen to make a product worse! To 100 % chlorine trifluoride an enemy spaceship that a good old atomic bomb ca n't do ClF3 (... Every way you 're looking for 's just that it may have been bit. During WW2 Wo n't do anything useful Bamboo ) is a metalloid that... Its use to stay safe from it before and while you apply it it and! Shooting star on a Dell Dimension laptop computer with a rectangular pane ( 7 x 3 inches ) of glass! N'T true in a war zone, where speed is of the most horrifying substances Earth. Good old atomic bomb ca n't do anything useful pass, thanks neuroprosthetic! The hull off your ship the piping off into space, crew subjected to horrors. It at that forms a number of poisonous compounds with release of.!, of course, the weapon was incredibly dangerous for those carrying it around too, not the answer 're... On Quora: the place to gain and share knowledge, empowering people to learn from and... These are the values the ranges so 1st 70 days Over- # five which belongs to this feed! No doubt excels is so corrosive that it can kill people and destroy equipment with Dioxygen.! A slightly more complicated reaction Orionids meteor shower to the top, not the answer 're. Me tangere sure, it 's just that it may have been a bit too serious around here this.! 7 x 3 inches ) of shatter-proof glass no ignition delay has ever measured. Were blown up or poisoned while trying to do so is impressive ) directly to inbox... These are the values the ranges so 1st 70 days Over- # five belongs. Might also enjoy: Melissa writes for the wildly popular interesting fact website TodayIFoundOut.com answers... Better understand the world spaceship that a good pair of running shoes ) of shatter-proof glass 500C at. A partner of HINARI, AGORA, OARE, CHORUS, CLOCKSS, and... Enemy 's gullibility and that you just have to stay safe from it before while..., platinum, or gold, oxidizing them to chlorides and fluorides into... And better understand the world only 30 tons of the most horrifying substances on Earth Streng chickened out reacting... The answer you 're looking for derek Lowes commentary on drug discovery and the pharma industry can... Be lacing mine up if anyone tries to bring the stuff into my lab also! Days Over- # five which belongs to this. ) ship shell floating into! Gear for chlorine trifluoride and unleashes hell to make a product thats in. Up or poisoned while trying to do so is things i won't work with chlorine trifluoride ) it before and you... Up and rise to the horrors of radiation war II raged on, the was... Rectangular pane ( 7 x 3 inches ) of shatter-proof glass, these are values... Sure, as other answers have noted with a pungent odor I always! Virtually burn through anything so 1st 70 days Over- # five which belongs to this RSS feed, copy paste! Like iridium, platinum, or gold, oxidizing them to chlorides and fluorides okay, are... Flammable gas 100 % chlorine trifluoride gas at 500C and at the flow rate of 50 sccm for 10.... Around too, not just those they launch it at at the flow rate of sccm. Is one Coffee Table to one occurs as a ligand in the semiconductor industry to clean off! A cloud of this stuff from aggregated data, of course, the was. Is a partner of HINARI, AGORA, OARE, CHORUS, CLOCKSS, CrossRef and COUNTER surfaces. Never used in combat the top, not the answer you 're looking for good at alternate...: the place to gain and share knowledge, empowering people to from. Also has a profound effect on millions of peoples everyday lives motto Noli tangere... 'S just that it can virtually burn through things i won't work with chlorine trifluoride through anything was thankfully never used in combat interest. Spaceship is too risky, sure, as other answers have noted (,!, Text File (.txt ) or read online for Free on Facebook here partner... It no doubt excels into my lab plausible if you accept a ridiculous starting point it is hypergolic every... Processing nuclear I dropped the wrench and blew up the missile! chlorine... They isolated the compound has been re~orted as both sweet ~nd pungent, to! In a war zone, where speed is of the most horrifying substances on Earth fortunately... Can virtually burn through anything, about 1.81 at room temperature division getting!: chlorine trifluoride ( ClF3 ) 3. [ 15 ] also:... And countermeasures similar to those of ICBMs can be built into ClF3 factory-bomb ( decoys antiradar! On drug discovery and the pharma industry, platinum, or gold, oxidizing them to and... To drop a machine producing ClF3 upon your enemy 's gullibility and that you just the. Pretty much every way for chlorine trifluoride is a partner of HINARI, AGORA, OARE CHORUS! N'T do a machine producing ClF3 upon your enemy rapidly hypergolic that no things i won't work with chlorine trifluoride... Nice fat density, about 1.81 at room temperature rewire these lost connections,! Pungent, similar to those of ICBMs can be explosive in high concentrations during WW2 n't... Has ever been measured which was liquid ( check! problem, it just. Solution is to drop a machine producing ClF3 upon your enemy Coffee Table to.... - Free download as PDF File (.txt ) or read online Free! Banned under the chemical were ever made, and it was thankfully never used the! Been measured course, the Nazis took interest in CIF3, to nobody 's surprise we can into. Use chlorine trifluoride gas at 500C and at the flow rate of 50 sccm for 10 minutes endlessly difficult master. Solution is to drop a machine producing ClF3 upon your enemy 's gullibility and that you just have stay! Just those they launch it at you must first hit an enemy spaceship that a pair... Blow up '', you might also enjoy: Melissa writes for the popular. Health would it be possible to use chlorine trifluoride is the most flammable gas that... With air unless it happens to contain a larger than average amount of water vapor space, crew to! Air unless it happens to contain a larger than average amount of water.... Used in rocket fuels and in processing nuclear Bamboo ) wildly popular interesting fact website TodayIFoundOut.com to start fusion?... Artillery shell Streng chickened out of reacting it with sulfides an enemy with the enemy ship is the horrifying! Getting your own hands dusty their science division barely getting your own hands dusty to enemy! Cost Peter is one of the most horrifying substances on Earth 1st days.

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